Yes, it can be used with all cases and genders, and both numbers, of the relative pronoun. The verb is usually subjunctive.
“There are men whom we left behind” – sunt quos reliquerimus, or maybe, since a specific group of men would be understood, sunt quos reliquimus.
This is a type of relative clause that Allen & Greenough labels a “relative clause of characteristic”: sec. 535a:
a. A Relative Clause of Characteristic is used after general expressions of existence or non-existence, including questions which imply a negative.
So especially with sunt quī, there are [some] who; quis est quī, who is there who?—
“ sunt quī discessum animī ā corpore putent esse mortem ” (Tusc. 1.18) , there are some who think that the departure of soul from body constitutes death.
“erant quī cēnsērent ” (B. C. 2.30) , there were some who were of the opinion, etc.
“ erant quī Helvidium miserārentur ” (Tac. Ann. 16.29) , there were some who pitied Helvidius. [Cf. est cum (N.3, below).]
“ quis est quī id nōn maximīs efferat laudibus ” (Lael. 24) , who is there that does not extol it with the highest praise?
“nihil videō quod timeam ” (Fam. 9.16.3) , I see nothing to fear.
“nihil est quod adventum nostrum extimēscās ” (Fam. 9.26.4) , there is no reason why you should dread my coming.
“ unde agger comportārī posset nihil erat reliquum ” (B. C. 2.15) , there was nothing left from which an embankment could be got together.
[*] Note 1.–After general negatives like nēmō est quī , the Subjunctive is regular; after general affirmatives like sunt quī , it is the prevailing construction, but the Indicative sometimes occurs; after multī (nōn nūllī, quīdam) sunt quī , and similar expressions in which the antecedent is partially defined, the choice of mood depends on the shade of meaning which the writer wishes to express:—
“ sunt bēstiae quaedam in quibus inest aliquid simile virtūtis ” (Fin. 5.38) , there are certain animals in which there is something like virtue.
“ But,—inventī multī sunt quī vītam prōfundere prō patriā parātī essent ” (Off. 1.84) , many were found of such a character as to be ready to give their lives for their country.
[*] Note 2.–Characteristic clauses with sunt quī etc. are sometimes called Relative Clauses with an Indefinite Antecedent, but are to be carefully distinguished from the Indefinite Relative in protasis (§ 520).
[*] Note 3.–The phrases est cum , fuit cum , etc. are used like est quī , sunt quī : as,— “ac fuit cum mihi quoque initium requiēscendī fore iūstum arbitrārer” (De Or. 1.1) , and there was a time when I thought a beginning of rest would be justifiable on my part.
http://www.perseus.tufts.edu/hopper/text?doc=AG+535&fromdoc=Perseus%3Atext%3A1999.04.0001