I can´t decide which word it goes with. One guess is that it makes substantive the final word of the snip, πεπληρωμένον, and encloses other words in the attributive position. But I can´t justify this.
It’s not possible to have such mental disposition (lit. to be thus disposed in his γνώμη) for someone (τὸν, “the person”) not filled with many fine sayings. τὸν μὴ … πεπεληρωμένον the subject of the infinitive (μή making it conditional, “unless”).