εῑμι

εῑμι has future meaning but what about ἁπειμι, ἕξειμι etc?

Yes, ἄπειμι (ibo) serve as the future of ἀπέρχομαι, ἔξειμι (ibo) as the future of ἐξέρχομαι

Regularly in Attic compound+εἶμι has future sense. But LSJ points out some exceptions: “the pres. sense is sts. found … in compds. (προσ-) A.Eu.242, (ἐπ-) Th.4.61, (συν-) Str.3.2.2.”